Journal: Helvetica Chimica Acta
Article Title: 3D‐Printing inside the Glovebox: A Versatile Tool for Inert‐Gas Chemistry Combined with Spectroscopy
doi: 10.1002/hlca.201500502
Figure Lengend Snippet: Reaction of cyclohexanone ( 5 ) with TMSB r. a ) Determination of the reaction rate constant k . Error bars are calculated from uncertainties of the integral values in the NMR spectra. b ) 13 C‐ NMR Spectra measured in flask F8 directly after printing and discharging the flask from the glovebox (bottom), and after 120, 210, and 300 min as well as control measurement of the isolated reaction solution in a glass NMR tube (top).
Article Snippet: All operations with air sensitive compounds were carried out at a high‐vacuum line (< 10 −6 mbar) using Schlenk techniques and in a glovebox ( M. Braun , Labmaster 130 , M. Braun Inertgas‐Systeme GmbH, Garching, Germany) under N 2 .
Techniques: Control, Isolation